Real Madrid’s UEFA Champions League fixtures for 2013/14.
| Date | Versus | Home/Away | Score |
| 17 September | Galatasaray | Away | 1-6 |
| 2 October | Copenhagen | Home | 4-0 |
| 23 October | Juventus | Home | 2-1 |
| 7 November | Juventus | Away | 2-2 |
| 27 November | Galatasaray | Home | 4-1 |
| 10 December | Copenhagen | Away | 0-2 |
| 26 February | Schalke 04 | Away | 1-6 |
| 18 March | Schalke 04 | Home | 3-1 |
| 2 April | Borussia Dortmund | Home | 3-0 |
| 8 April | Borussia Dortmund | Away | 2-0 |
| 23 April | Bayern Munich | Home | 1-0 |
| 29 April | Bayern Munich | Away | 0-4 |
| 24 May | Atletico Madrid | Neutral | 4-1 |