Real Madrid’s UEFA Champions League fixtures for 2012/13.
| Date | Versus | Home/Away | Score |
| 18 September | Manchester City | Home | 3-2 |
| 3 October | Ajax | Away | 1-4 |
| 24 October | Borussia Dortmund | Away | 2-1 |
| 6 November | Borussia Dortmund | Home | 2-2 |
| 21 November | Manchester City | Away | 1-1 |
| 4 December | Ajax | Home | 4-1 |
| 13 February | Manchester United | Home | 1-1 |
| 5 March | Manchester United | Away | 1-2 |
| 3 April | Galatasaray | Home | 3-0 |
| 9 April | Galatasaray | Away | 3-2 |
| 24 April | Borussia Dortmund | Away | 4-1 |
| 30 April | Borussia Dortmund | Home | 2-0 |